| 2026-10-03 | UFC 332: Silva vs. Wang | Women’s Flyweight | Natália Silva def. Wang Cong title | Decision (unanimous) (48–47, 48–47, 49–46) | 5 | 5:00 |
| 2025-11-15 | UFC 322: Della Maddalena vs. Makhachev | Women’s Flyweight | Valentina Shevchenko def. Zhang Weili title | Decision (unanimous) (50–45, 50–45, 50–45) | 5 | 5:00 |
| 2025-05-10 | UFC 315: Muhammad vs. Della Maddalena | Women’s Flyweight | Valentina Shevchenko def. Manon Fiorot title | Decision (unanimous) (48–47, 48–47, 48–47) | 5 | 5:00 |
| 2024-09-14 | UFC 306: O'Malley vs. Dvalishvili | Women’s Flyweight | Valentina Shevchenko def. Alexa Grasso title | Decision (unanimous) (50–45, 50–45, 50–45) | 5 | 5:00 |
| 2023-09-16 | UFC Fight Night: Grasso vs. Shevchenko 2 | Women’s Flyweight | Alexa Grasso vs. Valentina Shevchenko title | Draw (split) (48–47, 47–48, 47–47) | 5 | 5:00 |
| 2023-03-04 | UFC 285: Jones vs. Gane | Women’s Flyweight | Alexa Grasso def. Valentina Shevchenko title | Submission (face crank) | 4 | 4:34 |
| 2022-06-12 | UFC 275: Teixeira vs. Procházka | Women’s Flyweight | Valentina Shevchenko def. Taila Santos title | Decision (split) (48–47, 47–48, 49–46) | 5 | 5:00 |
| 2021-09-25 | UFC 266: Volkanovski vs. Ortega | Women’s Flyweight | Valentina Shevchenko def. Lauren Murphy title | TKO (elbows and punches) | 4 | 4:00 |
| 2021-04-24 | UFC 261: Usman vs. Masvidal 2 | Women’s Flyweight | Valentina Shevchenko def. Jéssica Andrade title | TKO (elbows) | 2 | 3:19 |
| 2020-11-21 | UFC 255: Figueiredo vs. Perez | Women’s Flyweight | Valentina Shevchenko def. Jennifer Maia title | Decision (unanimous) (49–46, 49–46, 49–46) | 5 | 5:00 |
| 2020-02-08 | UFC 247: Jones vs. Reyes | Women’s Flyweight | Valentina Shevchenko def. Katlyn Chookagian title | TKO (elbows and punches) | 3 | 1:03 |
| 2019-08-10 | UFC Fight Night: Shevchenko vs. Carmouche 2 | Women’s Flyweight | Valentina Shevchenko def. Liz Carmouche title | Decision (unanimous) (50–45, 50–45, 50–45) | 5 | 5:00 |
| 2019-06-08 | UFC 238: Cejudo vs. Moraes | Women’s Flyweight | Valentina Shevchenko def. Jessica Eye title | KO (head kick) | 2 | 0:26 |
| 2018-12-08 | UFC 231: Holloway vs. Ortega | Women’s Flyweight | Valentina Shevchenko def. Joanna Jędrzejczyk title | Decision (unanimous) (49–46, 49–46, 49–46) | 5 | 5:00 |
| 2017-12-01 | The Ultimate Fighter: A New World Champion Finale | Women’s Flyweight | Nicco Montaño def. Roxanne Modafferi title | Decision (unanimous) (50–45, 49–46, 49–46) | 5 | 5:00 |