| 2013-10-09 | UFC Fight Night: Maia vs. Shields | Welterweight | Rousimar Palhares def. Mike Pierce | Submission (heel hook) | 1 | 0:31 |
| 2012-12-15 | UFC on FX: Sotiropoulos vs. Pearson | Middleweight | Hector Lombard def. Rousimar Palhares | KO (punches) | 1 | 3:38 |
| 2012-05-05 | UFC on Fox: Diaz vs. Miller | Middleweight | Alan Belcher def. Rousimar Palhares | TKO (punches and elbows) | 1 | 4:18 |
| 2012-01-14 | UFC 142: Aldo vs. Mendes | Middleweight | Rousimar Palhares def. Mike Massenzio | Submission (heel hook) | 1 | 1:03 |
| 2011-08-27 | UFC 134: Silva vs. Okami | Middleweight | Rousimar Palhares def. Dan Miller | Decision (unanimous) (29–27, 30–27, 30–25) | 3 | 5:00 |
| 2011-03-03 | UFC Live: Sanchez vs. Kampmann | Middleweight | Rousimar Palhares def. David Branch | Submission (kneebar) | 2 | 1:44 |
| 2010-09-15 | UFC Fight Night: Marquardt vs. Palhares | Middleweight | Nate Marquardt def. Rousimar Palhares | TKO (punches) | 1 | 3:28 |
| 2010-03-27 | UFC 111: St-Pierre vs. Hardy | Middleweight | Rousimar Palhares def. Tomasz Drwal | Submission (heel hook) | 1 | 0:45 |
| 2009-12-12 | UFC 107: Penn vs. Sanchez | Middleweight | Rousimar Palhares def. Lucio Linhares | Submission (heel hook) | 2 | 3:21 |
| 2009-01-17 | UFC 93: Franklin vs. Henderson | Middleweight | Rousimar Palhares def. Jeremy Horn | Decision (unanimous) (30–27, 30–27, 30–27) | 3 | 5:00 |
| 2008-09-06 | UFC 88: Breakthrough | Middleweight | Dan Henderson def. Rousimar Palhares | Decision (unanimous) (30–27, 30–27, 29–28) | 3 | 5:00 |
| 2008-05-24 | UFC 84: Ill Will | Middleweight | Rousimar Palhares def. Ivan Salaverry | Submission (armbar) | 1 | 2:36 |