| 2020-10-24 | UFC 254: Khabib vs. Gaethje | Heavyweight | Tai Tuivasa def. Stefan Struve | KO (punches) | 1 | 4:59 |
| 2019-12-07 | UFC on ESPN: Overeem vs. Rozenstruik | Heavyweight | Ben Rothwell def. Stefan Struve | TKO (punches) | 2 | 4:57 |
| 2019-02-23 | UFC Fight Night: Błachowicz vs. Santos | Heavyweight | Stefan Struve def. Marcos Rogério de Lima | Submission (arm-triangle choke) | 2 | 2:21 |
| 2018-07-22 | UFC Fight Night: Shogun vs. Smith | Heavyweight | Marcin Tybura def. Stefan Struve | Decision (unanimous) (30–27, 30–27, 29–28) | 3 | 5:00 |
| 2018-03-03 | UFC 222: Cyborg vs. Kunitskaya | Heavyweight | Andrei Arlovski def. Stefan Struve | Decision (unanimous) (29–28, 29–28, 30–27) | 3 | 5:00 |
| 2017-09-02 | UFC Fight Night: Volkov vs. Struve | Heavyweight | Alexander Volkov def. Stefan Struve | TKO (punches) | 3 | 3:30 |
| 2016-10-08 | UFC 204: Bisping vs. Henderson 2 | Heavyweight | Stefan Struve def. Daniel Omielańczuk | Submission (D'Arce choke) | 2 | 1:41 |
| 2016-05-08 | UFC Fight Night: Overeem vs. Arlovski | Heavyweight | Stefan Struve def. Antônio Silva | TKO (elbows) | 1 | 0:16 |
| 2015-11-15 | UFC 193: Rousey vs. Holm | Heavyweight | Jared Rosholt def. Stefan Struve | Decision (unanimous) (29–28, 29–28, 29–28) | 3 | 5:00 |
| 2015-08-01 | UFC 190: Rousey vs. Correia | Heavyweight | Stefan Struve def. Antônio Rodrigo Nogueira | Decision (unanimous) (30–27, 30–27, 30–27) | 3 | 5:00 |
| 2014-12-13 | UFC on Fox: dos Santos vs. Miocic | Heavyweight | Alistair Overeem def. Stefan Struve | KO (punches) | 1 | 4:13 |
| 2013-03-03 | UFC on Fuel TV: Silva vs. Stann | Heavyweight | Mark Hunt def. Stefan Struve | TKO (punches) | 3 | 1:44 |
| 2012-09-29 | UFC on Fuel TV: Struve vs. Miocic | Heavyweight | Stefan Struve def. Stipe Miocic | TKO (punches) | 2 | 3:50 |
| 2012-05-26 | UFC 146: dos Santos vs. Mir | Heavyweight | Stefan Struve def. Lavar Johnson | Submission (armbar) | 1 | 1:05 |
| 2012-02-15 | UFC on Fuel TV: Sanchez vs. Ellenberger | Heavyweight | Stefan Struve def. Dave Herman | TKO (punches) | 2 | 3:52 |
| 2011-10-01 | UFC Live: Cruz vs. Johnson | Heavyweight | Stefan Struve def. Pat Barry | Submission (triangle choke) | 2 | 3:22 |
| 2011-05-28 | UFC 130: Rampage vs. Hamill | Heavyweight | Travis Browne def. Stefan Struve | KO (punch) | 1 | 4:11 |
| 2010-12-11 | UFC 124: St-Pierre vs. Koscheck 2 | Heavyweight | Stefan Struve def. Sean McCorkle | TKO (punches) | 1 | 3:55 |
| 2010-08-07 | UFC 117: Silva vs. Sonnen | Heavyweight | Stefan Struve def. Christian Morecraft | KO (punches) | 2 | 0:22 |
| 2010-03-31 | UFC Fight Night: Florian vs. Gomi | Heavyweight | Roy Nelson def. Stefan Struve | TKO (punches) | 1 | 0:39 |
| 2009-12-12 | UFC 107: Penn vs. Sanchez | Heavyweight | Stefan Struve def. Paul Buentello | Decision (majority) (29–28, 29–28, 28–28) | 3 | 5:00 |
| 2009-10-24 | UFC 104: Machida vs. Shogun | Heavyweight | Stefan Struve def. Chase Gormley | Submission (triangle choke) | 1 | 4:04 |
| 2009-06-13 | UFC 99: The Comeback | Heavyweight | Stefan Struve def. Denis Stojnić | Submission (rear-naked choke) | 2 | 2:37 |
| 2009-02-21 | UFC 95: Sanchez vs. Stevenson | Heavyweight | Junior dos Santos def. Stefan Struve | TKO (punches) | 1 | 0:54 |