| 2017-07-22 | UFC on Fox: Weidman vs. Gastelum | Middleweight | Eryk Anders def. Rafael Natal | KO (punches) | 1 | 2:54 |
| 2016-11-12 | UFC 205: Alvarez vs. McGregor | Middleweight | Tim Boetsch def. Rafael Natal | TKO (punches) | 1 | 3:22 |
| 2016-04-23 | UFC 197: Jones vs. Saint Preux | Middleweight | Robert Whittaker def. Rafael Natal | Decision (unanimous) (29–28, 30–27, 30–27) | 3 | 5:00 |
| 2016-01-30 | UFC on Fox: Johnson vs. Bader | Middleweight | Rafael Natal def. Kevin Casey | TKO (punches) | 3 | 3:37 |
| 2015-05-23 | UFC 187: Johnson vs. Cormier | Middleweight | Rafael Natal def. Uriah Hall | Decision (split) (29–28, 28–29, 29–28) | 3 | 5:00 |
| 2015-01-31 | UFC 183: Silva vs. Diaz | Middleweight | Rafael Natal def. Tom Watson | Decision (unanimous) (30–27, 30–27, 30–26) | 3 | 5:00 |
| 2014-09-05 | UFC Fight Night: Jacaré vs. Mousasi | Middleweight | Rafael Natal def. Chris Camozzi | Decision (split) (28–29, 29–28, 29–28) | 3 | 5:00 |
| 2014-05-10 | UFC Fight Night: Brown vs. Silva | Middleweight | Ed Herman def. Rafael Natal | Decision (unanimous) (30–27, 29–28, 29–28) | 3 | 5:00 |
| 2013-11-06 | UFC: Fight for the Troops 3 | Middleweight | Tim Kennedy def. Rafael Natal | KO (punches) | 1 | 4:40 |
| 2013-09-04 | UFC Fight Night: Teixeira vs. Bader | Middleweight | Rafael Natal def. Tor Troéng | Decision (unanimous) (30–27, 30–27, 29–28) | 3 | 5:00 |
| 2013-05-18 | UFC on FX: Belfort vs. Rockhold | Middleweight | Rafael Natal def. João Zeferino | Decision (unanimous) (30–27, 29–28, 29–28) | 3 | 5:00 |
| 2013-01-26 | UFC on Fox: Johnson vs. Dodson | Middleweight | Rafael Natal def. Sean Spencer | Submission (arm-triangle choke) | 3 | 2:13 |
| 2012-07-11 | UFC on Fuel TV: Muñoz vs. Weidman | Middleweight | Andrew Craig def. Rafael Natal | KO (head kick) | 2 | 4:52 |
| 2012-02-04 | UFC 143: Diaz vs. Condit | Middleweight | Rafael Natal def. Michael Kuiper | Decision (unanimous) (30–27, 30–27, 29–28) | 3 | 5:00 |
| 2011-08-06 | UFC 133: Evans vs. Ortiz | Middleweight | Rafael Natal def. Paul Bradley | Decision (unanimous) (30–27, 29–28, 29–28) | 3 | 5:00 |
| 2010-12-11 | UFC 124: St-Pierre vs. Koscheck 2 | Middleweight | Rafael Natal vs. Jesse Bongfeldt | Draw (majority) (28–28, 28–28, 29–28) | 3 | 5:00 |
| 2010-09-15 | UFC Fight Night: Marquardt vs. Palhares | Middleweight | Rich Attonito def. Rafael Natal | Decision (unanimous) (29–28, 29–28, 30–27) | 3 | 5:00 |